JPH01261444A - 光沢と耐衝撃性に優れたポリスチレン樹脂組成物 - Google Patents
光沢と耐衝撃性に優れたポリスチレン樹脂組成物Info
- Publication number
- JPH01261444A JPH01261444A JP63087305A JP8730588A JPH01261444A JP H01261444 A JPH01261444 A JP H01261444A JP 63087305 A JP63087305 A JP 63087305A JP 8730588 A JP8730588 A JP 8730588A JP H01261444 A JPH01261444 A JP H01261444A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- particles
- gloss
- modified polystyrene
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 17
- 229920005990 polystyrene resin Polymers 0.000 title claims abstract description 11
- 239000002245 particle Substances 0.000 claims abstract description 76
- 239000004793 Polystyrene Substances 0.000 claims abstract description 31
- 229920002223 polystyrene Polymers 0.000 claims abstract description 31
- 229920001971 elastomer Polymers 0.000 claims abstract description 27
- 239000005060 rubber Substances 0.000 claims abstract description 25
- 229920000642 polymer Polymers 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 14
- 241001237745 Salamis Species 0.000 claims description 4
- 235000015175 salami Nutrition 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 11
- 239000005062 Polybutadiene Substances 0.000 abstract description 9
- 229920002857 polybutadiene Polymers 0.000 abstract description 9
- 238000006116 polymerization reaction Methods 0.000 abstract description 4
- 125000003118 aryl group Chemical group 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000000178 monomer Substances 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- 238000012662 bulk polymerization Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract description 2
- 238000013019 agitation Methods 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000001746 injection moulding Methods 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 230000007423 decrease Effects 0.000 description 7
- 238000003756 stirring Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- -1 0-methylstyrene Chemical compound 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 239000005063 High cis polybutadiene Substances 0.000 description 1
- 239000005064 Low cis polybutadiene Substances 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- MMSLOZQEMPDGPI-UHFFFAOYSA-N p-Mentha-1,3,5,8-tetraene Chemical compound CC(=C)C1=CC=C(C)C=C1 MMSLOZQEMPDGPI-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63087305A JPH01261444A (ja) | 1988-04-11 | 1988-04-11 | 光沢と耐衝撃性に優れたポリスチレン樹脂組成物 |
| CA000595991A CA1335524C (en) | 1988-04-11 | 1989-04-07 | Rubber-modified polystyrene resin composition |
| US07/335,373 US5039714A (en) | 1988-04-11 | 1989-04-10 | Rubber-modified polystyrene resin composition |
| EP89200897A EP0337569B2 (en) | 1988-04-11 | 1989-04-10 | Rubber-modified polystyrene resin composition |
| DE1989604796 DE68904796T2 (de) | 1988-04-11 | 1989-04-10 | Kautschukmodifizierte Polystyrolharzzusammensetzung. |
| KR1019890004774A KR920001046B1 (ko) | 1986-10-29 | 1989-04-11 | 고무-변성된 폴리스티렌 수지 조성물 |
| TW078102842A TW197460B (en]) | 1986-10-29 | 1989-04-17 | |
| SG113094A SG113094G (en) | 1988-04-11 | 1994-08-13 | Rubber-modified polystyrene resin composition |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63087305A JPH01261444A (ja) | 1988-04-11 | 1988-04-11 | 光沢と耐衝撃性に優れたポリスチレン樹脂組成物 |
| SG113094A SG113094G (en) | 1988-04-11 | 1994-08-13 | Rubber-modified polystyrene resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01261444A true JPH01261444A (ja) | 1989-10-18 |
| JPH0525897B2 JPH0525897B2 (en]) | 1993-04-14 |
Family
ID=26428594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63087305A Granted JPH01261444A (ja) | 1986-10-29 | 1988-04-11 | 光沢と耐衝撃性に優れたポリスチレン樹脂組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01261444A (en]) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0238435A (ja) * | 1988-07-28 | 1990-02-07 | Idemitsu Petrochem Co Ltd | スチレン系樹脂組成物 |
| JPH0238437A (ja) * | 1988-07-28 | 1990-02-07 | Idemitsu Petrochem Co Ltd | 高光沢耐衝撃性スチレン系樹脂組成物 |
| JPH03220252A (ja) * | 1990-01-26 | 1991-09-27 | Idemitsu Petrochem Co Ltd | 高光沢耐衝撃性スチレン系樹脂組成物 |
| JPH03220256A (ja) * | 1990-01-26 | 1991-09-27 | Idemitsu Petrochem Co Ltd | スチレン系樹脂組成物 |
| JPH03223359A (ja) * | 1990-01-30 | 1991-10-02 | Idemitsu Petrochem Co Ltd | ゴム変性スチレン系樹脂組成物 |
| JPH03223358A (ja) * | 1990-01-30 | 1991-10-02 | Idemitsu Petrochem Co Ltd | スチレン系樹脂から成る射出成形品 |
| US5473014A (en) * | 1992-03-23 | 1995-12-05 | Mitsui Toatsu Chemicals, Incorporated | Rubber modified styrenic resin composition having high gloss and impact strength |
| WO2003033559A1 (en) * | 2001-10-19 | 2003-04-24 | Cheil Industries Inc. | Method of preparing rubber modified polystyrene resin composition with high gloss and impact resistance |
| KR100411088B1 (ko) * | 2001-08-17 | 2003-12-18 | 제일모직주식회사 | 내열성과 표면광택성이 우수한 스티렌계 수지조성물 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51139850A (en) * | 1975-05-15 | 1976-12-02 | Labofina Sa | High impact polystylene composition and process for production thereof |
| US4493922A (en) * | 1980-09-20 | 1985-01-15 | Basf Aktiengesellschaft | Impact-resistant thermoplastic molding material |
| JPH0463099A (ja) * | 1990-06-29 | 1992-02-28 | Kyocera Corp | コイル付き圧電型発音体及びその製造方法 |
-
1988
- 1988-04-11 JP JP63087305A patent/JPH01261444A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51139850A (en) * | 1975-05-15 | 1976-12-02 | Labofina Sa | High impact polystylene composition and process for production thereof |
| US4493922A (en) * | 1980-09-20 | 1985-01-15 | Basf Aktiengesellschaft | Impact-resistant thermoplastic molding material |
| JPH0463099A (ja) * | 1990-06-29 | 1992-02-28 | Kyocera Corp | コイル付き圧電型発音体及びその製造方法 |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0238435A (ja) * | 1988-07-28 | 1990-02-07 | Idemitsu Petrochem Co Ltd | スチレン系樹脂組成物 |
| JPH0238437A (ja) * | 1988-07-28 | 1990-02-07 | Idemitsu Petrochem Co Ltd | 高光沢耐衝撃性スチレン系樹脂組成物 |
| JPH03220252A (ja) * | 1990-01-26 | 1991-09-27 | Idemitsu Petrochem Co Ltd | 高光沢耐衝撃性スチレン系樹脂組成物 |
| JPH03220256A (ja) * | 1990-01-26 | 1991-09-27 | Idemitsu Petrochem Co Ltd | スチレン系樹脂組成物 |
| JPH03223359A (ja) * | 1990-01-30 | 1991-10-02 | Idemitsu Petrochem Co Ltd | ゴム変性スチレン系樹脂組成物 |
| JPH03223358A (ja) * | 1990-01-30 | 1991-10-02 | Idemitsu Petrochem Co Ltd | スチレン系樹脂から成る射出成形品 |
| US5473014A (en) * | 1992-03-23 | 1995-12-05 | Mitsui Toatsu Chemicals, Incorporated | Rubber modified styrenic resin composition having high gloss and impact strength |
| KR100411088B1 (ko) * | 2001-08-17 | 2003-12-18 | 제일모직주식회사 | 내열성과 표면광택성이 우수한 스티렌계 수지조성물 |
| WO2003033559A1 (en) * | 2001-10-19 | 2003-04-24 | Cheil Industries Inc. | Method of preparing rubber modified polystyrene resin composition with high gloss and impact resistance |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0525897B2 (en]) | 1993-04-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |